First choice after the the battle box? I would suggest skarlok, a great model for any caster, and either the book or cards. The book gives you more of the background but the cards give you all the model rule, which will allow you to proxy different models before you buy.
Then to get to 25pts I'd suggest a unit. Most people will probably suggest bane thralls, they are the easiest to use, but any of their units are great. A lot of the strength in Cryx is found in their units & solos